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Material Safety Data Sheet
Sodium iodate

ACC# 21335
Section 1 - Chemical Product and Company Identification

MSDS Name: Sodium iodate
Catalog Numbers: AC201760000, AC201761000, AC201765000, AC419560050, AC419565000, NC9048278, NC9626448, S322-100, S76798
Synonyms:
Iodic acid, sodium salt.
Company Identification:

              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call:
201-796-7100
Emergency Number:
201-796-7100
For CHEMTREC assistance, call:
800-424-9300
For International CHEMTREC assistance, call:
703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
7681-55-2 Sodium iodate >99 231-672-5

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: fine crystalline powder.
Danger! Strong oxidizer. Contact with other material may cause a fire. Causes eye, skin, and respiratory tract irritation. Harmful if swallowed.
Target Organs: Respiratory system, eyes, skin.


Potential Health Effects
Eye: Contact with eyes may cause severe irritation, and possible eye burns. May cause eye injury.
Skin: Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion: Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation: May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. May be harmful if inhaled.
Chronic: Prolonged or repeated exposure may cause gastrointestinal irritation and kidney damage. Chronic exposure can lead to iodism characterized by headache, excess salivation, nasal discharge, conjunctivitis, laryngitis, bronchitis, stomatitis, enlarged submaxillary glands, and skin rashes. Chronic ingestion may cause central nervous system failure.

Section 4 - First Aid Measures


Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately.
Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustion generates toxic fumes. Use water with caution and in flooding amounts. Oxidizer. Greatly increases the burning rate of combustible materials. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Contact professional fire-fighters immediately.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 0; Instability: 1; Special Hazard: OX

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Remove all sources of ignition. Do not use combustible materials such as paper towels to clean up spill.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with clothing and other combustible materials. Do not get on skin or in eyes. Avoid ingestion and inhalation.
Storage: Do not store near combustible materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from reducing agents.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Sodium iodate none listed none listed none listed

OSHA Vacated PELs: Sodium iodate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate gloves to prevent skin exposure.
Clothing: Wear a chemical apron. Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Crystalline powder
Appearance: white - fine
Odor: odorless
pH: Neutral in sol.
Vapor Pressure: Negligible.
Vapor Density: Not available.
Evaporation Rate:Negligible.
Viscosity: Not available.
Boiling Point: Not applicable.
Freezing/Melting Point:Decomposes
Decomposition Temperature:Not available.
Solubility: Soluble in water.
Specific Gravity/Density:4.28
Molecular Formula:INaO3
Molecular Weight:197.89

Section 10 - Stability and Reactivity


Chemical Stability: Stable. However, may decompose if heated.
Conditions to Avoid: High temperatures, dust generation, combustible materials, organic materials.
Incompatibilities with Other Materials: Strong reducing agents, finely powdered metals, hydrogen peroxide, sulfides (inorganic, e.g. ferric sulfide, lead sulfide, sodium sulfide), combustible materials, flammable liquids.
Hazardous Decomposition Products: Hydrogen iodide, sodium oxide, iodine.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information


RTECS#:      
CAS# 7681-55-2: NN1400000
LD50/LC50:
CAS# 7681-55-2:
     Oral, mouse: LD50 = 505 mg/kg;
.

Carcinogenicity:
CAS# 7681-55-2: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Mutagenicity: No information available.
Neurotoxicity: No information available.
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: OXIDIZING SOLID, N.O.S. OXIDIZING SOLID NOS (SODIUM IODATE)
Hazard Class: 5.1 5.1
UN Number: UN1479 UN1479
Packing Group: II II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 7681-55-2 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 7681-55-2: immediate, fire.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 7681-55-2 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     XN O
Risk Phrases:

     R 22 Harmful if swallowed.
     R 36/37/38 Irritating to eyes, respiratory system and skin.
     R 8 Contact with combustible material may cause fire.

Safety Phrases:

     S 17 Keep away from combustible material.
     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 37/39 Wear suitable gloves and eye/face protection.

WGK (Water Danger/Protection)

     CAS# 7681-55-2: 1
Canada - DSL/NDSL
     CAS# 7681-55-2 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 11/16/1998
Revision #4 Date: 2/15/2008

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.